Metal-organic framework-based catalysts for hydrogen production from liquid-phase chemical hydrides

Yao，Qilu1; Zhang，Xiaolei1; Lu，Zhang Hui1; Xu，Qiang2,3

2023-10-15

10.1016/j.ccr.2023.215302

Coordination Chemistry Reviews   Impact Factor & Quartile

0010-8545

Hydrogen is a clean, sustainable, and efficient energy carrier. However, the safe and controllable storage and evolution of hydrogen for practical applications remain challenging. Chemical hydrides, such as metal borohydride, ammonia borane, hydrous hydrazine, hydrazine borane, and formic acid, have been studied as promising hydrogen carriers because of their high hydrogen capacity, excellent safety, easy transportation and storage, and mild dehydrogenation conditions. Developing efficient, selective, and stable catalysts for H production from chemical hydrides becomes very important. Recently, metal–organic framework (MOF) materials have been intensively exploited in catalytic hydrogen production reactions on account of their diverse composition, adjustable pore structure, large surface area, high porosity, and tailorable chemistry. Herein, we outline significant progress achieved in MOFs and their composites and derivatives toward catalytic hydrogen production from liquid-phase chemical hydrides. The state-of-the-art synthesis methods and advanced characterization of MOF-based catalysts and their catalytic activities in hydrogen production, are introduced. Finally, the opportunities and challenges for the future development of MOF-based catalysts toward dehydrogenation of chemical hydrides are briefly summarized and prospected. It is believed that this review will provide important understanding and enlightenment for hydrogen evolution from liquid-phase chemical hydrides over MOF-based catalysts.

Catalysis Chemical hydrides Hydrogen production Metal-organic frameworks

English

Others

Booz Allen Foundation[20212ACB204009];Booz Allen Foundation[20212BCJL23059];Booz Allen Foundation[2021ZT09C064];Booz Allen Foundation[2022YFA1503900];Booz Allen Foundation[22162013];Booz Allen Foundation[22162014];

CHEMISTRY

2-s2.0-85165976488

Scopus

1.Institute of Advanced Materials (IAM),National Engineering Research Center for Carbohydrate Synthesis,Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education,Key Laboratory of Energy Catalysis and Conversion of Nanchang,College of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang,330022,China
2.Shenzhen Key Laboratory of Micro/Nano-Porous Functional Materials (SKLPM),SUSTech-Kyoto University Advanced Energy Materials Joint Innovation Laboratory (SKAEM-JIL),Department of Chemistry and Department of Materials Science and Engineering,Southern University of Science and Technology (SUSTech),Shenzhen,518055,China
3.Institute for Integrated Cell-Material Sciences (iCeMS),Kyoto University,Kyoto,Yoshida, Sakyo-ku,606-8501,Japan

Yao，Qilu,Zhang，Xiaolei,Lu，Zhang Hui,et al. Metal-organic framework-based catalysts for hydrogen production from liquid-phase chemical hydrides[J]. Coordination Chemistry Reviews,2023,493.

Yao，Qilu,Zhang，Xiaolei,Lu，Zhang Hui,&Xu，Qiang.(2023).Metal-organic framework-based catalysts for hydrogen production from liquid-phase chemical hydrides.Coordination Chemistry Reviews,493.

Yao，Qilu,et al."Metal-organic framework-based catalysts for hydrogen production from liquid-phase chemical hydrides".Coordination Chemistry Reviews 493(2023).