| Title | Towards the total synthesis of aleurodiscal |
| Author | |
| Corresponding Author | Xu，Jing |
| Publication Years | 2023-07-28
|
| DOI | |
| Source Title | |
| ISSN | 0040-4039
|
| EISSN | 1873-3581
|
| Volume | 125 |
| Abstract | Aleurodiscal is one of the representative members of the isopropyl trans-hydrindane sesterterpenoid family. Herein, we describe our efforts towards the synthesis of a complex sesterterpenoid, aleurodiscal. The key precursor of the Cope rearrangement was concisely synthesized from a known bicyclic starting material in 13 linear steps. Our approach highlighted a Van Leusen homologation reaction and an oxidative rearrangement of a tertiary carbinol. |
| Keywords | |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | NSFC["21971104","22271136"]
; Shenzhen Key Laboratory of Small Molecule Drug Discovery and Synthesis[ZDSYS20190902093215877]
; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]
; Guangdong Innovative Program[2019BT02Y335]
; Key research projects in colleges and universities in Guangdong Province[2021ZDZX2035]
; Shenzhen Nobel Prize Scientists Laboratory Project[C17783101]
; Innovative Team of Universities in Guangdong Province[2020KCXTD016]
; Guangdong Natural Science Foundation[2022A1515010456]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Organic
|
| WOS Accession No | WOS:001035716900001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Scopus EID | 2-s2.0-85163158673
|
| Data Source | Scopus
|
| Citation statistics |
Cited Times [WOS]:0
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/559804 |
| Department | Department of Chemistry 深圳格拉布斯研究院 |
| Affiliation | Shenzhen Grubbs Institute and Department of Chemistry and Guangdong Provincial Key Laboratory of Catalysis and Shenzhen Key Laboratory of Small Molecule Drug Discovery and Synthesis,Southern University of Science and Technology,Shenzhen,518055,China |
| First Author Affilication | Department of Chemistry; Shenzhen Grubbs Institute |
| Corresponding Author Affilication | Department of Chemistry; Shenzhen Grubbs Institute |
| First Author's First Affilication | Department of Chemistry; Shenzhen Grubbs Institute |
| Recommended Citation GB/T 7714 |
Zhao，Hai Xiao,Xu，Jing. Towards the total synthesis of aleurodiscal[J]. Tetrahedron Letters,2023,125.
|
| APA |
Zhao，Hai Xiao,&Xu，Jing.(2023).Towards the total synthesis of aleurodiscal.Tetrahedron Letters,125.
|
| MLA |
Zhao，Hai Xiao,et al."Towards the total synthesis of aleurodiscal".Tetrahedron Letters 125(2023).
|
| Files in This Item: | There are no files associated with this item. | |||||
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