A bottleable super-electron-donor for catalytic borylation of aryl halides

Ming，Wenbo1,4; Xu，Yashi1; Xiang，Libo2,3; Ye，Qing1,2,3

2023-05-24

10.1039/d3cc01435e

Chemical Communications   Impact Factor & Quartile

1359-7345

1364-548X

[(Dpp-bian)B(DMAP)] (dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene, DMAP = 4-(dimethylamino)pyridine), a bottleable super electron donor (SED), was demonstrated to serve as a SED catalyst in the borylation of aryl iodides, bromides, and the more challenging chlorides. Apart from installing Bpin from Bpin, the SED-catalyzed borylation protocol is also applicable for installing Bdan from Bpin-Bdan. The radical mechanism has been confirmed by the radical trapping and radical clock experiments.

SCI ; CCR

English

NI Journal Papers ; NI论文

First ; Corresponding

DFG[517941121]

Chemistry

Chemistry, Multidisciplinary

WOS:001000286200001

ROYAL SOC CHEMISTRY

CHEMISTRY

2-s2.0-85163820577

Scopus

1.Department of Chemistry,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China
2.Institute for Inorganic Chemistry,Julius-Maximilians-Universität Würzburg,Würzburg,Am Hubland,97074,Germany
3.Institute for Sustainable Chemistry & Catalysis with Boron,Julius-Maximilians-Universität Würzburg,Würzburg,Am Hubland,97074,Germany
4.Joint Laboratory for Translational Cancer Research of Chinese Medicine of the Ministry of Education of the People’s Republic of China,International Institute for Translational Chinese Medicine,Guangzhou University of Chinese Medicine,Guangzhou,510006gb,China

Ming，Wenbo,Xu，Yashi,Xiang，Libo,et al. A bottleable super-electron-donor for catalytic borylation of aryl halides[J]. Chemical Communications,2023,59(49):7651-7654.

Ming，Wenbo,Xu，Yashi,Xiang，Libo,&Ye，Qing.(2023).A bottleable super-electron-donor for catalytic borylation of aryl halides.Chemical Communications,59(49),7651-7654.

Ming，Wenbo,et al."A bottleable super-electron-donor for catalytic borylation of aryl halides".Chemical Communications 59.49(2023):7651-7654.