| Title | Anthryl-functionalized cyanide-bridged Fe/Co cubes |
| Author | |
| Publication Years | 2023
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| DOI | |
| Source Title | |
| ISSN | 1477-9226
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| EISSN | 1477-9234
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| Abstract | Two anthryl-functionalized cyanide-bridged [FeCo] cube complexes, [(pzTp)Fe(CN)Co(TpEtOAn)][OTf]·8MeCN·7EtO (1) and [NEt][(pzTp)Fe(CN)Co(TpEtOAn)][OTf]·5MeCN·2EtO (2) (pzTp = tetrapyrazolylborate, TpEtOAn = 2,2,2-tris-(pyrazol-1-yl)ethoxy(9-methyl-anthracene)), were synthesized and characterized. The crystallographic study revealed that the [FeCo] cubes are arranged into a linear supramolecular chain through significant anthryl-anthryl π-π stacking interactions in complex 1, whereas a zigzag supramolecular 1D assembly is observed in 2. The magnetic measurements showed that both compounds exhibited incomplete transitions from the paramagnetic {Fe(μ-CN)Co} state to the diamagnetic {Fe(μ-CN)Co} state at about 200 K. The luminescence measurement of 1 in solution revealed an enhancement of the emission upon dilution or addition of perfluoronaphthalene (PFN) molecules, which could be attributed to the suppression of the aggregation-caused quenching (ACQ) effect, suggesting possible aggregation of the cube units in the solution. |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | First
|
| Funding Project | This work was supported by the National Natural Science Foundation of China (no. 21901101 and 21671095) and the Stable Support Plan Program of the Shenzhen Natural Science Fund (no. 20200925151834005).["21671095","20200925151834005"]
; null[21901101]
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| WOS Research Area | Chemistry
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| WOS Subject | Chemistry, Inorganic & Nuclear
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| WOS Accession No | WOS:001056950800001
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| Publisher | |
| ESI Research Field | CHEMISTRY
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| Scopus EID | 2-s2.0-85170676773
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| Data Source | Scopus
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| Citation statistics |
Cited Times [WOS]:0
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| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/560029 |
| Department | Department of Chemistry |
| Affiliation | Department of Chemistry,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China |
| First Author Affilication | Department of Chemistry |
| First Author's First Affilication | Department of Chemistry |
| Recommended Citation GB/T 7714 |
Liu，Qi,Cheng，Yue,Liu，Shihao,et al. Anthryl-functionalized cyanide-bridged Fe/Co cubes[J]. Dalton Transactions,2023.
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| APA |
Liu，Qi,Cheng，Yue,Liu，Shihao,Chen，Zi Yi,&Zhang，Yuan Zhu.(2023).Anthryl-functionalized cyanide-bridged Fe/Co cubes.Dalton Transactions.
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| MLA |
Liu，Qi,et al."Anthryl-functionalized cyanide-bridged Fe/Co cubes".Dalton Transactions (2023).
|
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