BN Analogue of Butadiyne: A Platform for Dinitrogen Release and Reduction
|Corresponding Author||Liu，Liu Leo; Kong，Lingbing|
Exploration of the metallomimetic chemistry of main group elements is of the utmost importance from the perspective of both fundamental research and potential applications. Here, we report the synthesis, bonding analysis, and reactivities of an isolable diiminoborane, Mes*B≡N─N≡BMes* (Mes* = 2,4,6-tri-tert-butylphenyl) (1), a BN analogue of butadiyne. This species is characterized by a conjugated B≡N─N≡B moiety, a structural feature that enables the controlled release of N when it is exposed to organic nitriles. Furthermore, the N unit in 1 could be reduced to an ammonium salt via cleavage of the BN triple bond. Our work shows a rare example of an unsaturated BN system, serving as a platform for both the release and reduction of N. This discovery opens new pathways and holds substantial influence on the future design of functional main group N species.
NI Journal Papers
NSFC["22271174","21971144","22101114","22271132"] ; Taishan Scholar Project of SD Province of China[tsqn202211007] ; NSF of SD Province[ZR2019ZD46] ; Multidisciplinary Research and Innovation Team of Young Scholars of SDU[2020QNQT007] ; Guangdong Innovation amp; Entrepreneurial Research Team Program[2021ZT09C278]
|WOS Research Area|
|WOS Accession No|
Cited Times [WOS]:0
|Document Type||Journal Article|
|Department||Department of Chemistry|
1.School of Chemistry and Chemical Engineering,Shandong University,Jinan,250100,China
2.Department of Chemistry and Research Center for Chemical Biology and Omics Analysis,College of Science,Southern University of Science and Technology,Shenzhen,518055,China
3.School of Chemistry and Chemical Engineering,Liaocheng University,Liaocheng,252059,China
4.State Key Laboratory of Elemento-Organic Chemistry,Nankai University,Tianjin,300071,China
|Corresponding Author Affilication||Department of Chemistry; College of Science|
Guo，Rui,Hu，Chaopeng,Li，Qianli,et al. BN Analogue of Butadiyne: A Platform for Dinitrogen Release and Reduction[J]. Journal of the American Chemical Society,2023.
Guo，Rui,Hu，Chaopeng,Li，Qianli,Liu，Liu Leo,Tung，Chen Ho,&Kong，Lingbing.(2023).BN Analogue of Butadiyne: A Platform for Dinitrogen Release and Reduction.Journal of the American Chemical Society.
Guo，Rui,et al."BN Analogue of Butadiyne: A Platform for Dinitrogen Release and Reduction".Journal of the American Chemical Society (2023).
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