Ultrafast Synthesis of Nasicon Solid Electrolytes for Sodium-Metal Batteries
|Corresponding Author||Shi，Siqi; Wan，Jiayu|
NASICON-structured solid-state electrolytes (SSEs) are highly promising materials for sodium solid-state metal batteries (NaSMBs). However, the current synthesis methods are often labor-intensive and inefficient, consuming a significant amount of energy and time. Here, an ultrafast high-temperature synthesis (UHS) technique is successfully demonstrated to directly synthesize NASICON-type SSEs from mixed precursor powders, reducing the synthesis time from hours to merely seconds. The intermediate with a NaPO structure plays a critical role in the rapid synthesis of NASICON-type SSEs, ultimately leading to the formation of the final NASICON phase. Moreover, the UHS-synthesizes NASICON-type NaZrLuSiPO (NZLSP) exhibits high room temperature ionic conductivity of 7.7 × 10 S cm, approximately three times that of the undoped NaZrSiPO (NZSP). The Na|NZLSP|Na symmetric cell can sustain highly stable cycling for over 4800 h. This study provides a novel insight and validation in the precise and targeted synthesis of complex oxide solid-state electrolytes.
National Natural Science Foundation of China["52272215","52102313"]
|WOS Research Area|
Chemistry ; Energy & Fuels ; Materials Science ; Physics
Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
|WOS Accession No|
Cited Times [WOS]:0
|Document Type||Journal Article|
|Department||Department of Mechanical and Energy Engineering|
1.Department of Mechanical and Energy Engineering,Southern University of Science and Technology,Shenzhen,518055,China
2.School of Materials Science and Engineering,Xiangtan University,Xiangtan,Hunan,411105,China
3.Energy Storage and Distributed Resources Division,Lawrence Berkeley National Laboratory,Berkeley,94720,United States
4.School of Materials Science and Engineering,Shanghai University,Shanghai,200444,China
5.Future Battery Research Center,Global Institute of Future Technology,Shanghai Jiaotong University,Shanghai,200240,China
|First Author Affilication||Department of Mechanical and Energy Engineering|
|First Author's First Affilication||Department of Mechanical and Energy Engineering|
Zuo，Daxian,Yang，Lin,Zou，Zheyi,et al. Ultrafast Synthesis of Nasicon Solid Electrolytes for Sodium-Metal Batteries[J]. Advanced Energy Materials,2023.
Zuo，Daxian.,Yang，Lin.,Zou，Zheyi.,Li，Shen.,Feng，Yitian.,...&Wan，Jiayu.(2023).Ultrafast Synthesis of Nasicon Solid Electrolytes for Sodium-Metal Batteries.Advanced Energy Materials.
Zuo，Daxian,et al."Ultrafast Synthesis of Nasicon Solid Electrolytes for Sodium-Metal Batteries".Advanced Energy Materials (2023).
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