Organocatalytic (1+4)-Annulations of MBH Adducts with Electron-Deficient Systems

Chen，Xuling; Li，Pengfei

2023

10.1002/tcr.202300152

Chemical Record   Impact Factor & Quartile

1527-8999

1528-0691

Benefited from the rapid development of MBH reaction, the reaction of MBH adducts have been established as the most synthetically useful transformations. However, compared with the well-established allylic alkylations and (3+2)-annulations, the (1+4)-annulations of MBH adducts have not developed rapidly until recently. As a helpful complement to the (3+2)-annulations of MBH adducts, the (1+4)-annulations of MBH adducts opens a robust access to structurally diverse five-membered carbo- and heterocycles. This paper summarizes recent advances in organocatalytic (1+4)-annulations using MBH adducts as 1 C-synthons for the construction of functionalized five-membered carbo- and heterocycles.

annulation enone imine MBH adduct organocatalysis

SCI

English

First ; Corresponding

National Natural Science Foundation of China[21871128]

Chemistry

Chemistry, Multidisciplinary

WOS:001003418300001

WILEY-V C H VERLAG GMBH

CHEMISTRY

2-s2.0-85161379386

Scopus

Department of Chemistry,Guangdong Provincial Key Laboratory of Catalysis,Guangming Advanced Research Institute,College of Science,Southern University of Science and Technology,Shenzhen,1088 Xueyuan Blvd., Nanshan District, Guangdong,518055,China

Chen，Xuling,Li，Pengfei. Organocatalytic (1+4)-Annulations of MBH Adducts with Electron-Deficient Systems[J]. Chemical Record,2023.

Chen，Xuling,&Li，Pengfei.(2023).Organocatalytic (1+4)-Annulations of MBH Adducts with Electron-Deficient Systems.Chemical Record.

Chen，Xuling,et al."Organocatalytic (1+4)-Annulations of MBH Adducts with Electron-Deficient Systems".Chemical Record (2023).