Enhanced Performance and Stability of Q-PHJ Devices through Strategic Placement of Dimerized Acceptors

Tan, Pu1,2; Chen, Hui1,2; Wang, Hengtao1,2; Lai, Xue1,2,3; Zhu, Yulin1,2,3; Shen, Xiangyu1,2; Pu, Mingrui1,2; Lai, Hanjian1,2; Zhang, Sen4; Ma, Wei4; He, Feng1,2,5

2023-09-01

10.1002/adfm.202305608

ADVANCED FUNCTIONAL MATERIALS   Impact Factor & Quartile

1616-301X

1616-3028

["Oligomeric acceptors are an effective & pi;-conjugate extension for small molecules because they effectively combine the advantages of polymeric and small molecular acceptors. The choice of linker group and oligomer position is however crucial for the efficient expression of & pi;-expansion advantages. Here, vinylene is chosen as the linker group and three oligomeric acceptors are produced with different connecting positions or end-groups. Under illumination, the dimer acceptor dBTIC-& gamma;V-BO achieves the best power conversion efficiencies of 17.14% and a T80 lifetime of 2150 h amongst quasi-planar heterojunction devices, which are much higher and more stable than the directly connected dimers dBTIC & gamma;-EH or dBTIC-& delta;V-BO. These results indicate that the oligomerization of small molecules with an appropriate linker group in the & gamma;-position is an effective strategy with which to improve the photovoltaic performance and stability of organic solar cells, and significantly promote their commercialization.","Oligomerization is an important strategy that can elevate the photovoltaic properties and the stability of organic solar cells. With a connection at the & gamma;-position of the IC end group, dBTIC-& gamma;V-BO shows the best planarity and delivers the highest efficiency of 17.14% and the most objective stability of T80 lifetime of 2150 h in Q-PHJ devices of those three oligomeric accepters. image"]

oligomerization photovoltaic performance quasi-planar heterojunction stability vinylene

SCI

English

NI Journal Papers

First ; Corresponding

National Natural Science Foundation of China["22225504","21975115"] ; Shenzhen Fundamental Research Program["JCYJ20200109140801751","JCYJ20210324120010028"] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002]

Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics

Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter

WOS:001067383100001

WILEY-V C H VERLAG GMBH

MATERIALS SCIENCE

Web of Science

1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China
2.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China
3.Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150001, Peoples R China
4.Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
5.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China

Tan, Pu,Chen, Hui,Wang, Hengtao,et al. Enhanced Performance and Stability of Q-PHJ Devices through Strategic Placement of Dimerized Acceptors[J]. ADVANCED FUNCTIONAL MATERIALS,2023.

Tan, Pu.,Chen, Hui.,Wang, Hengtao.,Lai, Xue.,Zhu, Yulin.,...&He, Feng.(2023).Enhanced Performance and Stability of Q-PHJ Devices through Strategic Placement of Dimerized Acceptors.ADVANCED FUNCTIONAL MATERIALS.

Tan, Pu,et al."Enhanced Performance and Stability of Q-PHJ Devices through Strategic Placement of Dimerized Acceptors".ADVANCED FUNCTIONAL MATERIALS (2023).