中文版 | English
Title

A 3D modelling study on all vanadium redox flow battery at various operating temperatures

Author
Corresponding AuthorZhao, Tianshou; Ni, Meng
Publication Years
2023-11-01
DOI
Source Title
ISSN
0360-5442
EISSN
1873-6785
Volume282
Abstract
To understand whether the optimization of the operating/electrode structural parameters are temperature dependent, a 3D numerical model is developed and validated to gain insight into the impact of practical operating temperature (273.15 K-323.15 K) on vanadium redox flow battery (VRFB) performance, in which the property parameters are from published experimental data. The operating temperature is found significantly influence the optimal design of VRFBs. Increasing the inlet flow rate and state of charge (SOC), decreasing the electrode porosity and fibre diameter can all improve the battery performance with interdigitated flow channels, and the improvement increases with increasing temperature. In contrast, decreasing the fibre diameter or porosity increases the flow resistance and costs higher pump consumption, which is more pronounced at a lower temperature due to higher electrolyte viscosity. The effect of electrode thickness is also different at various temperatures. The gradient porosity electrode is applied in VRFB with interdigitated flow channels. The electrochemical performance of VRFB with gradient electrode (porosity increases from 0.8 at channel side to 0.93 at membrane side) performs similarly with the VRFB with 0.8 porosity electrode, while the pressure drop is reduced by 40% at all temperature. This model provides a deep understanding of effects of a wide range of working temperature on the optimization of operating/electrode parameters and on the VRFBs' performance.
Keywords
URL[Source Record]
Indexed By
Language
English
SUSTech Authorship
Corresponding
Funding Project
Research Grants Council, University Grants Committee, Hong Kong SAR[T23-601/17-R]
WOS Research Area
Thermodynamics ; Energy & Fuels
WOS Subject
Thermodynamics ; Energy & Fuels
WOS Accession No
WOS:001071611000001
Publisher
ESI Research Field
ENGINEERING
Data Source
Web of Science
Citation statistics
Cited Times [WOS]:1
Document TypeJournal Article
Identifierhttp://kc.sustech.edu.cn/handle/2SGJ60CL/575820
DepartmentDepartment of Mechanical and Energy Engineering
Affiliation
1.Hong Kong Polytech Univ, Res Inst Sustainable Urban Dev RISUD, Dept Bldg & Real Estate, Kowloon, Hong Kong, Peoples R China
2.Hong Kong Polytech Univ, Res Inst Smart Energy RISE, Hong Kong, Peoples R China
3.Univ Sci & Technol China USTC, Dept Thermal Sci & Energy Engn, Hefei 230026, Anhui, Peoples R China
4.Chongqing Univ Technol, Dept Phys & Energy, Chongqing Key Lab Green Energy Mat Technol & Syst, Chongqing 400054, Peoples R China
5.Southern Univ Sci & Technol, Dept Mech & Energy Engn, Shenzhen 518055, Peoples R China
Corresponding Author AffilicationDepartment of Mechanical and Energy Engineering
First Author's First AffilicationDepartment of Mechanical and Energy Engineering
Recommended Citation
GB/T 7714
He, Qijiao,Li, Zheng,Zhao, Dongqi,et al. A 3D modelling study on all vanadium redox flow battery at various operating temperatures[J]. ENERGY,2023,282.
APA
He, Qijiao.,Li, Zheng.,Zhao, Dongqi.,Yu, Jie.,Tan, Peng.,...&Ni, Meng.(2023).A 3D modelling study on all vanadium redox flow battery at various operating temperatures.ENERGY,282.
MLA
He, Qijiao,et al."A 3D modelling study on all vanadium redox flow battery at various operating temperatures".ENERGY 282(2023).
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