| Title | Tunable Yellow to Near-Infrared Fluorescent Boron-Amino-Chelating Complexes with Stokes Shifts >100 nm |
| Author | |
| Corresponding Author | He, Jiang; Ou, Sha; Lu, Wei; Li, Kai |
| Publication Years | 2023-10-01
|
| DOI | |
| Source Title | |
| ISSN | 0022-3263
|
| EISSN | 1520-6904
|
| Abstract | A series of diphenylboron-chelating N-substituent 8-aminoquinoline, 5-aminoquinoxaline, and 1-aminophenazine were prepared. They exhibit lowest energy absorption peaks of 444-766 nm, emission peaks of 563-820 nm, and quantum yields of up to 46.5%. Electrochemical and theoretical studies indicate that the N-substituent mainly determines the HOMO and the framework determines the LUMO, thus allowing for a wide-tuning of absorptions/emissions. Intramolecular charge transfer transition leads to large Stokes shifts of up to 166 nm. One selected compound showed satisfactory cytocompatibility and cytoplasm-targeting cell imaging ability. |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | National Natural Science Foundation of China["21873044","22271196"]
; Guangdong Major Project of Basic and Applied Basic Research[2019B030302009]
; Youth Science and Technology Talents Growth Project of Guizhou Ordinary Colleges and Universities[KY [2022]219]
; Science and Technology Fund Project of Guizhou Provincial Health Commission[gzwkj2021-406]
; National Natural Science Foundation Cultivation Project of Guizhou Medical University[19NSP061]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Organic
|
| WOS Accession No | WOS:001076036700001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics |
Cited Times [WOS]:0
|
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/575877 |
| Department | Department of Chemistry |
| Affiliation | 1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 2.Songshan Lake Mat Lab, Frontier Res Ctr, Funct Coordinat Mat Grp, Dongguan 523808, Peoples R China 3.Guizhou Med Univ, Sch Biol & Engn, Sch Hlth Med Modern Ind, Guiyang 550025, Peoples R China 4.Shenzhen Univ, Coll Mat Sci & Engn, Shenzhen 518055, Peoples R China 5.Shenzhen Univ, Coll Phys & Optoelect Engn, Shenzhen 518060, Peoples R China |
| First Author Affilication | Department of Chemistry |
| Corresponding Author Affilication | Department of Chemistry |
| First Author's First Affilication | Department of Chemistry |
| Recommended Citation GB/T 7714 |
He, Jiang,Chang, Xiaoyong,Zou, Chao,et al. Tunable Yellow to Near-Infrared Fluorescent Boron-Amino-Chelating Complexes with Stokes Shifts >100 nm[J]. JOURNAL OF ORGANIC CHEMISTRY,2023.
|
| APA |
He, Jiang.,Chang, Xiaoyong.,Zou, Chao.,Yu, Yanqin.,Han, Shuang.,...&Li, Kai.(2023).Tunable Yellow to Near-Infrared Fluorescent Boron-Amino-Chelating Complexes with Stokes Shifts >100 nm.JOURNAL OF ORGANIC CHEMISTRY.
|
| MLA |
He, Jiang,et al."Tunable Yellow to Near-Infrared Fluorescent Boron-Amino-Chelating Complexes with Stokes Shifts >100 nm".JOURNAL OF ORGANIC CHEMISTRY (2023).
|
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