| Title | Direct Visualization of CO Interaction on Oxygen Poisoned Co(0001) |
| Author | |
| Corresponding Author | Huang, Chuanqi; Guo, Qing; Yang, Wenshao |
| Publication Years | 2023-10-12
|
| DOI | |
| Source Title | |
| ISSN | 1948-7185
|
| Volume | 14Issue:42 |
| Abstract | The poisoning of catalysts has always been a vital issue in catalytic reactions. In this study, direct observation of the interaction of CO and oxygen-poisoned Co(0001) has been achieved with scanning tunneling microscopy (STM), temperature-programmed desorption (TPD), and density functional theory calculation. A two-stage adsorption process of CO on a well-prepared p(2x2)-O layer covered Co(0001) was directly visualized. With increasing annealing time at a certain temperature after the CO dosage, the ordered (2 x 2) pattern formed in the first stage can be recovered, suggesting the weak interaction of CO with the O-covered Co(0001) surface in the latter stage. Compared to the clean Co(0001) surface, on an oxygen-poisoned surface, no further reaction was observed, illustrating the poisoning of the catalyst. Moreover, TPD results are in good agreement with the STM observation; a desorption energy of 0.35 eV is evaluated with a simple but accurate scheme. |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| Important Publications | NI Journal Papers
|
| SUSTech Authorship | Corresponding
|
| Funding Project | National Natural Science Foundation of China["21973084","22373088"]
; Zhejiang Provincial Natural Science Foundation of China[LZ22B030003]
; Shenzhen Science and Technology Innovation Committee[20220814164755002]
|
| WOS Research Area | Chemistry
; Science & Technology - Other Topics
; Materials Science
; Physics
|
| WOS Subject | Chemistry, Physical
; Nanoscience & Nanotechnology
; Materials Science, Multidisciplinary
; Physics, Atomic, Molecular & Chemical
|
| WOS Accession No | WOS:001090575500001
|
| Publisher | |
| Data Source | Web of Science
|
| Citation statistics | |
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/582761 |
| Department | Department of Chemistry |
| Affiliation | 1.Zhejiang Normal Univ, Hangzhou Inst Adv Studies, Hangzhou 311231, Peoples R China 2.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China 3.Inst Adv Sci Facil, Shenzhen 518107, Guangdong, Peoples R China |
| Corresponding Author Affilication | Department of Chemistry |
| Recommended Citation GB/T 7714 |
Fang, Zihao,Bao, Anran,Lai, Yuemiao,et al. Direct Visualization of CO Interaction on Oxygen Poisoned Co(0001)[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS,2023,14(42).
|
| APA |
Fang, Zihao.,Bao, Anran.,Lai, Yuemiao.,Yao, Lanlan.,Zeng, Ziling.,...&Yang, Wenshao.(2023).Direct Visualization of CO Interaction on Oxygen Poisoned Co(0001).JOURNAL OF PHYSICAL CHEMISTRY LETTERS,14(42).
|
| MLA |
Fang, Zihao,et al."Direct Visualization of CO Interaction on Oxygen Poisoned Co(0001)".JOURNAL OF PHYSICAL CHEMISTRY LETTERS 14.42(2023).
|
| Files in This Item: | There are no files associated with this item. | |||||
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