南方科技大学知识苑(SUSTech KC): Base-mediated carboxylation of <i>C</i>-nucleophiles with CO<sub>2</sub>

Title	Base-mediated carboxylation of C-nucleophiles with CO₂
Author	Luo, Yanlong 1; Huang, Wenbin2
Corresponding Author	Luo, Yanlong; Huang, Wenbin
Publication Years	2023-11-08
DOI	10.1039/d3ob01367g
Source Title	ORGANIC & BIOMOLECULAR CHEMISTRY Impact Factor & Quartile
ISSN	1477-0520
EISSN	1477-0539
Volume	21 Issue:43
Abstract	Carbon dioxide (CO2) is an available, abundant, and renewable C1 resource, which could be converted into value-added chemicals. Due to its inherent thermodynamic stability and kinetic inertness, it is difficult to realize its efficient utilization. Nevertheless, many elegant strategies for the utilization of CO2 have been developed using Lewis bases, frustrated Lewis pairs, hydroxyl-containing compounds, amino-group-containing compounds or transition metal catalysis. Among them, base-mediated carboxylation of C-nucleophiles is an environmentally friendly strategy for CO2 conversion, which is operationally simple, using low-toxicity bases and economical available promoters, without the use of complex ligands or cocatalysts. This review summarizes related work on the base-mediated carboxylation of C-nucleophiles with CO2, based on the effects of nucleophiles, promoters, additives, and solvents. The types of pronucleophile are categorized as follows: hydrocarbon with C(sp(3))-H, C(sp(2))-H or C(sp)-H bonds, organosilanes, organotin, organoboron, and N-tosylhydrazones. Typical mechanisms and applications of these carboxylation reactions are also depicted. Moreover, mechanistic comprehension of CO2 activation and conversion at a molecular level aims to further expand the repertoire of carboxylation transformations mediated by bases.
URL	[Source Record]
Indexed By	SCI
Language	English
SUSTech Authorship	Corresponding
Funding Project	Tianshui Normal University["TDJ2022-02","GJB2022-12"]
WOS Research Area	Chemistry
WOS Subject	Chemistry, Organic
WOS Accession No	WOS:001086217400001
Publisher	ROYAL SOC CHEMISTRY
ESI Research Field	CHEMISTRY
Data Source	Web of Science
Citation statistics
Document Type	Journal Article
Identifier	http://kc.sustech.edu.cn/handle/2SGJ60CL/582859
Department	Department of Chemistry
Affiliation	1.Tianshui Normal Univ, Sch Chem Engn & Technol, Tianshui 741001, Gansu, Peoples R China 2.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China
Corresponding Author Affilication	Department of Chemistry
Recommended Citation GB/T 7714	Luo, Yanlong,Huang, Wenbin. Base-mediated carboxylation of C-nucleophiles with CO₂[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2023,21(43).
APA	Luo, Yanlong,&Huang, Wenbin.(2023).Base-mediated carboxylation of C-nucleophiles with CO₂.ORGANIC & BIOMOLECULAR CHEMISTRY,21(43).
MLA	Luo, Yanlong,et al."Base-mediated carboxylation of C-nucleophiles with CO₂".ORGANIC & BIOMOLECULAR CHEMISTRY 21.43(2023).

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Base-mediated carboxylation of C-nucleophiles with CO2

Base-mediated carboxylation of C-nucleophiles with CO₂