| Title | Utilizing bis(imino)dihydroacridanide pincer ligands in p-block chemistry: synthesis and catalysis of an antimony monocation salt |
| Author | |
| Corresponding Author | Liu, Liu Leo |
| Publication Years | 2023-11-07
|
| DOI | |
| Source Title | |
| ISSN | 1477-9226
|
| EISSN | 1477-9234
|
| Volume | 52Issue:43 |
| Abstract | We present the synthesis and characterization of an Sb(iii) monocation salt stabilized by a bulky bis(imino)dihydroacridanide pincer ligand. The Lewis acidity of the Sb cation is quantified using the Guttmann-Beckett method and confirmed by its reaction with 4-dimethylaminopyridine, which forms a Lewis acid-base adduct. This Sb cation exhibits catalytic activity in the cyanosilylation of arylketones. The electronic structure of the Sb cation as well as the mechanism of the catalytic transformation are explored by density functional theory computations. |
| URL | [Source Record] |
| Indexed By | |
| Language | English
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | We gratefully acknowledge financial support from the National Natural Science Foundation of China (22271132; 22101114; 22301119; 22201122), Shenzhen Science and Technology Innovation Program (JCYJ20220530114806015), and Guangdong Provincial Key Laboratory["22271132","22101114","22301119","22201122"]
; National Natural Science Foundation of China[JCYJ20220530114806015]
; Shenzhen Science and Technology Innovation Program[2020B121201002]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Inorganic & Nuclear
|
| WOS Accession No | WOS:001085966800001
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics | |
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/582897 |
| Department | Department of Chemistry |
| Affiliation | 1.Southern Univ Sci & Technol, Coll Sci, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Coll Sci, Res Ctr Chem Biol & Om Anal, Shenzhen 518055, Peoples R China |
| First Author Affilication | Department of Chemistry; Southern University of Science and Technology |
| Corresponding Author Affilication | Department of Chemistry; Southern University of Science and Technology |
| First Author's First Affilication | Department of Chemistry |
| Recommended Citation GB/T 7714 |
Lan, Xiaofang,Zhang, Xin,Mei, Yanbo,et al. Utilizing bis(imino)dihydroacridanide pincer ligands in p-block chemistry: synthesis and catalysis of an antimony monocation salt[J]. DALTON TRANSACTIONS,2023,52(43).
|
| APA |
Lan, Xiaofang,Zhang, Xin,Mei, Yanbo,Hu, Chaopeng,&Liu, Liu Leo.(2023).Utilizing bis(imino)dihydroacridanide pincer ligands in p-block chemistry: synthesis and catalysis of an antimony monocation salt.DALTON TRANSACTIONS,52(43).
|
| MLA |
Lan, Xiaofang,et al."Utilizing bis(imino)dihydroacridanide pincer ligands in p-block chemistry: synthesis and catalysis of an antimony monocation salt".DALTON TRANSACTIONS 52.43(2023).
|
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