Cu-catalyzed borylative coupling enables desymmetrization of meso-dibromocycloalkenes

Zhan, Baoquan1,2,3; He, Chuan1,2

2023-09-21

10.1016/j.checat.2023.100761

CHEM CATALYSIS   Impact Factor & Quartile

2667-1093

In this issue of Chem Catalysis, Fananas-Mastral and co-workers report on the development of desymmetrization of meso-dibromo-cycloalkenes by using a copper-catalyzed borylative coupling with alkynes via a catalytically generated boron-substituted alkenylcop-per intermediate. This transformation gives access to a wide range of chiral cycloalkenes featuring stereodefined alkenyl boronate and bromide functionalities with high regio-, diastereo-, and enan-tioselectivity.

ESCI

English

First ; Corresponding

Chemistry

Chemistry, Physical

WOS:001082979400001

CELL PRESS

Web of Science

1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China
2.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Guangdong, Peoples R China
3.South Cent Minzu Univ, Sch Chem & Mat Sci, Wuhan 430074, Peoples R China

Zhan, Baoquan,He, Chuan. Cu-catalyzed borylative coupling enables desymmetrization of meso-dibromocycloalkenes[J]. CHEM CATALYSIS,2023,3(9).

Zhan, Baoquan,&He, Chuan.(2023).Cu-catalyzed borylative coupling enables desymmetrization of meso-dibromocycloalkenes.CHEM CATALYSIS,3(9).

Zhan, Baoquan,et al."Cu-catalyzed borylative coupling enables desymmetrization of meso-dibromocycloalkenes".CHEM CATALYSIS 3.9(2023).