| Title | Research Progress on Copper-Catalyzed Enantioselective Desymmetrization of Diols |
| Author | |
| Corresponding Author | Gu Qiangshuai; Liu Xinyuan |
| Publication Years | 2023-08-15
|
| DOI | |
| Source Title | |
| ISSN | 0567-7351
|
| Volume | 81Issue:8 |
| Abstract | Enantioselective desymmetrization of diols is an important method for the synthesis of complex enantioenriched alcohols, which has broad application prospects in medicinal chemistry, total synthesis, and materials science. In recent years, the use of copper catalysis to achieve diols' enantioselective desymmetrization has progressed rapidly because copper is inexpensive and readily available compared with other noble metal catalysts. Besides, copper undergoes a two-electron or single-electron transfer process in the catalytic cycle, and the rich oxidation states of copper provides the opportunity to solve some challenging problems. This review summarizes the research progress in this field according to the types of diols (meso diol and prochiral diol) and reactions together with a brief perspective. |
| Keywords | |
| URL | [Source Record] |
| Indexed By | |
| Language | Chinese
|
| SUSTech Authorship | First
; Corresponding
|
| Funding Project | National Natural Science Foundation of China["22025103","92256301","21831002","22101122","22001109","22271133","22201127"]
; National Key R&D Program of China["2021YFF0701604","2021YFF0701704"]
; Shenzhen Science and Technology Program["KQTD20210811090112004","JCYJ20220530115409020"]
|
| WOS Research Area | Chemistry
|
| WOS Subject | Chemistry, Multidisciplinary
|
| WOS Accession No | WOS:001071604900012
|
| Publisher | |
| ESI Research Field | CHEMISTRY
|
| Data Source | Web of Science
|
| Citation statistics | |
| Document Type | Journal Article |
| Identifier | http://kc.sustech.edu.cn/handle/2SGJ60CL/582973 |
| Department | Department of Chemistry 前沿与交叉科学研究院 深圳格拉布斯研究院 |
| Affiliation | 1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen 518055, Peoples R China 4.Great Bay Univ, Sch Sci, Dept Chem, Dongguan 523000, Peoples R China |
| First Author Affilication | Department of Chemistry; Shenzhen Grubbs Institute |
| Corresponding Author Affilication | Department of Chemistry; Academy for Advanced Interdisciplinary Studies; Shenzhen Grubbs Institute |
| First Author's First Affilication | Department of Chemistry |
| Recommended Citation GB/T 7714 |
Yu Zhanglong,Li Zhongliang,Yang Changjiang,et al. Research Progress on Copper-Catalyzed Enantioselective Desymmetrization of Diols[J]. ACTA CHIMICA SINICA,2023,81(8).
|
| APA |
Yu Zhanglong,Li Zhongliang,Yang Changjiang,Gu Qiangshuai,&Liu Xinyuan.(2023).Research Progress on Copper-Catalyzed Enantioselective Desymmetrization of Diols.ACTA CHIMICA SINICA,81(8).
|
| MLA |
Yu Zhanglong,et al."Research Progress on Copper-Catalyzed Enantioselective Desymmetrization of Diols".ACTA CHIMICA SINICA 81.8(2023).
|
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